| Subject |
Chemistry, Organic.
|
| Descript |
1 online resource (1261 p.) |
| Note |
Description based upon print version of record. |
| Contents |
Cover -- Contents -- Abbreviations -- Preface to the second edition -- Organic chemistry and this book -- 1 What is organic chemistry? -- Organic chemistry and you -- Organic compounds -- Organic chemistry and industry -- Organic chemistry and the periodic table -- Organic chemistry and this book -- Further reading -- 2 Organic structures -- Hydrocarbon frameworks and functional groups -- Drawing molecules -- Hydrocarbon frameworks -- Functional groups -- Carbon atoms carrying functional groups can be classified by oxidation level -- Naming compounds -- What do chemists really call compounds? |
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How should you name compounds? -- Further reading -- 3 Determining organic structures -- Introduction -- Mass spectrometry -- Mass spectrometry detects isotopes -- Atomic composition can be determined by high-resolution mass spectrometry -- Nuclear magnetic resonance -- Regions of the [sup(13)]C NMR spectrum -- Different ways of describing chemical shift -- A guided tour of the [sup(13)]C NMR spectra of some simple molecules -- The [sup(1)]H NMR spectrum -- Infrared spectra -- Mass spectra, NMR, and IR combined make quick identification possible |
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Double bond equivalents help in the search for a structure -- Looking forward to Chapters 13 and 18 -- Further reading -- 4 Structure of molecules -- Introduction -- Electrons occupy atomic orbitals -- Molecular orbitals-diatomic molecules -- Bonds between different atoms -- Hybridization of atomic orbitals -- Rotation and rigidity -- Conclusion -- Looking forward -- Further reading -- 5 Organic reactions -- Chemical reactions -- Nucleophiles and electrophiles -- Curly arrows represent reaction mechanisms -- Drawing your own mechanisms with curly arrows -- Further reading |
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6 Nucleophilic addition to the carbonyl group -- Molecular orbitals explain the reactivity of the carbonyl group -- Attack of cyanide on aldehydes and ketones -- The angle of nucleophilic attack on aldehydes and ketones -- Nucleophilic attack by 'hydride' on aldehydes and ketones -- Addition of organometallic reagents to aldehydes and ketones -- Addition of water to aldehydes and ketones -- Hemiacetals from reaction of alcohols with aldehydes and ketones -- Ketones also form hemiacetals -- Acid and base catalysis of hemiacetal and hydrate formation -- Bisulfite addition compounds |
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Further reading -- 7 Delocalization and conjugation -- Introduction -- The structure of ethene (ethylene, CH[sub(2)]=CH[sub(2)]) -- Molecules with more than one C=C double bond -- The conjugation of two π bonds -- UV and visible spectra -- The allyl system -- Delocalization over three atoms is a common structural feature -- Aromaticity -- Further reading -- 8 Acidity, basicity, and pK[sub(a)] -- Organic compounds are more soluble in water as ions -- Acids, bases, and pK[sub(a)] -- Acidity -- The definition of pK[sub(a)] -- Constructing a pK[sub(a)] scale -- Nitrogen compounds as acids and bases |
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Substituents affect the pK[sub(a)] |
| Note |
Unlimited number of concurrent users. UkHlHU |
| Alt author |
Greeves, Nick.
|
|
Warren, Stuart G.
|
| ISBN |
9780191666216 |
|
