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Author Scott, Robert A.
Title Applications of physical methods to inorganic and bioinorganic chemistry.
Publication Info Somerset : Wiley, 2013.
Edition 1st ed.


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Descript 1 online resource (598 p.)
Edition 1st ed.
Note Description based upon print version of record.
Contents Applications of Physical Methods to Inorganic and Bioinorganic Chemistry -- Copyright Page -- Contents -- List of Contributors -- Series Preface -- Volume Preface -- Circular Dichroism (CD) Spectroscopy -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Measuring CD Spectra -- 2.2 Choice of Cuvettes -- 3 Applications -- 3.1 Identification of Protein Secondary Structure -- 3.2 CD Spectra of: Complexes of the Group 8-10 Transition Metals -- 3.3 CD Spectra of Group 11 Metals -- 3.4 CD Spectra of Complexes involving Group 12 metals
3.5 CD Spectral Data from other Metal Complexes -- 3.6 Metallothioneins: a Special Case of a Metalloprotein with Highly Sensitive Metal-dependent CD Spectral Properties -- 4 Acknowledgments -- 5 Abbreviations and Acronyms -- 6 References -- Electrochemistry -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Electrode Reaction Fundamentals -- 2.2 Potentials of Electrochemical Reactions, E. -- 2.3 Electrochemical Cells and Practical Considerations -- 2.4 Electrochemical Processes -- 3 Applications -- 3.1 Potential Sweep Methods -- 3.2 Potential Step/Pulsed Methods
3.3 Hydrodynamic Methods -- 3.4 Bulk Electrolysis (BE) -- 3.5 Electrochemical Simulations -- 3.6 Correlation of Electrochemistry to Electronic Spectroscopy -- 3.7 Coupled Techniques -- 4 Acknowledgments -- 5 Abbreviations and Acronyms -- 6 Further Reading -- 7 References -- Electron Paramagnetic Resonance (EPR) Spectroscopy -- Method Summary -- 1 Introduction -- 1.1 History and Terminology -- 2 Relationship Between ''Spin'', Angular Momentum, and Magnetic Moment -- 3 Zeeman Interaction -- 4 Electrons in Atoms and Molecules -- 5 The EPR Experiment-Measuring ''g''
5.1 The EPR Spectrometer-How it Works -- 5.2 What Energy Is Used for Irradiation? -- 5.3 How Much Sample Is Needed? -- 5.4 Why the First Derivative? -- 5.5 Line Shape -- 5.6 Saturation and Spin Relaxation -- 6 The EPR Spectrometer-Setting the Parameters -- 7 Rapid Passage -- 8 Hyperfine Interaction-the Effect of Nuclear Spin -- 9 Anisotropy -- 10 Powder Spectra -- 11 Examples of S = 1/2 Signals in Metalloproteins -- 11.1 Sign of the Deviation of the g-factor from ge -- 11.2 Copper (Cu2+) -- 11.3 Vanadium (V4+) -- 11.4 Molybdenum (Mo5+) -- 11.5 Low-spin Heme (Fe3+) -- 11.6 Iron-Sulfur Clusters
12 S > 1/2 Spectra -- 12.1 The Energy Equation -- 12.2 Half-integer (Kramers) Systems -- 13 Example of S = 3/2 System-MoFe Protein of Nitrogenase -- 14 Example of S = 5/2 -- 14.1 Aquometmyoglobin -- 15 Integer-Spin (non-Kramers) Systems -- 16 Abbreviations and Acronyms -- 17 Related Articles -- 18 Further Reading -- 19 References -- Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Two-pulse ESEEM -- 2.2 Three-pulse ESEEM -- 2.3 Two-dimensional ESEEM -- 2.4 Practical Aspects of ESEEM Experiments
3 Application-Eseem Studies of Fe(II)/α-Ketoglutarate-Dependent Dioxygenases
Note 200 annual accesses. UkHlHU
ISBN 9781118625262
 Click on the terms below to find similar items in the catalogue
Author Scott, Robert A.
Series EIC Books
EIC Books
Subject Bioinorganic chemistry.
Chemistry, Inorganic.
Chemistry.
Alt author Lukehart, Charles M.
Descript 1 online resource (598 p.)
Edition 1st ed.
Note Description based upon print version of record.
Contents Applications of Physical Methods to Inorganic and Bioinorganic Chemistry -- Copyright Page -- Contents -- List of Contributors -- Series Preface -- Volume Preface -- Circular Dichroism (CD) Spectroscopy -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Measuring CD Spectra -- 2.2 Choice of Cuvettes -- 3 Applications -- 3.1 Identification of Protein Secondary Structure -- 3.2 CD Spectra of: Complexes of the Group 8-10 Transition Metals -- 3.3 CD Spectra of Group 11 Metals -- 3.4 CD Spectra of Complexes involving Group 12 metals
3.5 CD Spectral Data from other Metal Complexes -- 3.6 Metallothioneins: a Special Case of a Metalloprotein with Highly Sensitive Metal-dependent CD Spectral Properties -- 4 Acknowledgments -- 5 Abbreviations and Acronyms -- 6 References -- Electrochemistry -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Electrode Reaction Fundamentals -- 2.2 Potentials of Electrochemical Reactions, E. -- 2.3 Electrochemical Cells and Practical Considerations -- 2.4 Electrochemical Processes -- 3 Applications -- 3.1 Potential Sweep Methods -- 3.2 Potential Step/Pulsed Methods
3.3 Hydrodynamic Methods -- 3.4 Bulk Electrolysis (BE) -- 3.5 Electrochemical Simulations -- 3.6 Correlation of Electrochemistry to Electronic Spectroscopy -- 3.7 Coupled Techniques -- 4 Acknowledgments -- 5 Abbreviations and Acronyms -- 6 Further Reading -- 7 References -- Electron Paramagnetic Resonance (EPR) Spectroscopy -- Method Summary -- 1 Introduction -- 1.1 History and Terminology -- 2 Relationship Between ''Spin'', Angular Momentum, and Magnetic Moment -- 3 Zeeman Interaction -- 4 Electrons in Atoms and Molecules -- 5 The EPR Experiment-Measuring ''g''
5.1 The EPR Spectrometer-How it Works -- 5.2 What Energy Is Used for Irradiation? -- 5.3 How Much Sample Is Needed? -- 5.4 Why the First Derivative? -- 5.5 Line Shape -- 5.6 Saturation and Spin Relaxation -- 6 The EPR Spectrometer-Setting the Parameters -- 7 Rapid Passage -- 8 Hyperfine Interaction-the Effect of Nuclear Spin -- 9 Anisotropy -- 10 Powder Spectra -- 11 Examples of S = 1/2 Signals in Metalloproteins -- 11.1 Sign of the Deviation of the g-factor from ge -- 11.2 Copper (Cu2+) -- 11.3 Vanadium (V4+) -- 11.4 Molybdenum (Mo5+) -- 11.5 Low-spin Heme (Fe3+) -- 11.6 Iron-Sulfur Clusters
12 S > 1/2 Spectra -- 12.1 The Energy Equation -- 12.2 Half-integer (Kramers) Systems -- 13 Example of S = 3/2 System-MoFe Protein of Nitrogenase -- 14 Example of S = 5/2 -- 14.1 Aquometmyoglobin -- 15 Integer-Spin (non-Kramers) Systems -- 16 Abbreviations and Acronyms -- 17 Related Articles -- 18 Further Reading -- 19 References -- Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Two-pulse ESEEM -- 2.2 Three-pulse ESEEM -- 2.3 Two-dimensional ESEEM -- 2.4 Practical Aspects of ESEEM Experiments
3 Application-Eseem Studies of Fe(II)/α-Ketoglutarate-Dependent Dioxygenases
Note 200 annual accesses. UkHlHU
ISBN 9781118625262
Author Scott, Robert A.
Series EIC Books
EIC Books
Subject Bioinorganic chemistry.
Chemistry, Inorganic.
Chemistry.
Alt author Lukehart, Charles M.

Subject Bioinorganic chemistry.
Chemistry, Inorganic.
Chemistry.
Descript 1 online resource (598 p.)
Note Description based upon print version of record.
Contents Applications of Physical Methods to Inorganic and Bioinorganic Chemistry -- Copyright Page -- Contents -- List of Contributors -- Series Preface -- Volume Preface -- Circular Dichroism (CD) Spectroscopy -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Measuring CD Spectra -- 2.2 Choice of Cuvettes -- 3 Applications -- 3.1 Identification of Protein Secondary Structure -- 3.2 CD Spectra of: Complexes of the Group 8-10 Transition Metals -- 3.3 CD Spectra of Group 11 Metals -- 3.4 CD Spectra of Complexes involving Group 12 metals
3.5 CD Spectral Data from other Metal Complexes -- 3.6 Metallothioneins: a Special Case of a Metalloprotein with Highly Sensitive Metal-dependent CD Spectral Properties -- 4 Acknowledgments -- 5 Abbreviations and Acronyms -- 6 References -- Electrochemistry -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Electrode Reaction Fundamentals -- 2.2 Potentials of Electrochemical Reactions, E. -- 2.3 Electrochemical Cells and Practical Considerations -- 2.4 Electrochemical Processes -- 3 Applications -- 3.1 Potential Sweep Methods -- 3.2 Potential Step/Pulsed Methods
3.3 Hydrodynamic Methods -- 3.4 Bulk Electrolysis (BE) -- 3.5 Electrochemical Simulations -- 3.6 Correlation of Electrochemistry to Electronic Spectroscopy -- 3.7 Coupled Techniques -- 4 Acknowledgments -- 5 Abbreviations and Acronyms -- 6 Further Reading -- 7 References -- Electron Paramagnetic Resonance (EPR) Spectroscopy -- Method Summary -- 1 Introduction -- 1.1 History and Terminology -- 2 Relationship Between ''Spin'', Angular Momentum, and Magnetic Moment -- 3 Zeeman Interaction -- 4 Electrons in Atoms and Molecules -- 5 The EPR Experiment-Measuring ''g''
5.1 The EPR Spectrometer-How it Works -- 5.2 What Energy Is Used for Irradiation? -- 5.3 How Much Sample Is Needed? -- 5.4 Why the First Derivative? -- 5.5 Line Shape -- 5.6 Saturation and Spin Relaxation -- 6 The EPR Spectrometer-Setting the Parameters -- 7 Rapid Passage -- 8 Hyperfine Interaction-the Effect of Nuclear Spin -- 9 Anisotropy -- 10 Powder Spectra -- 11 Examples of S = 1/2 Signals in Metalloproteins -- 11.1 Sign of the Deviation of the g-factor from ge -- 11.2 Copper (Cu2+) -- 11.3 Vanadium (V4+) -- 11.4 Molybdenum (Mo5+) -- 11.5 Low-spin Heme (Fe3+) -- 11.6 Iron-Sulfur Clusters
12 S > 1/2 Spectra -- 12.1 The Energy Equation -- 12.2 Half-integer (Kramers) Systems -- 13 Example of S = 3/2 System-MoFe Protein of Nitrogenase -- 14 Example of S = 5/2 -- 14.1 Aquometmyoglobin -- 15 Integer-Spin (non-Kramers) Systems -- 16 Abbreviations and Acronyms -- 17 Related Articles -- 18 Further Reading -- 19 References -- Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy -- Method Summary -- 1 Introduction -- 2 Technical Background -- 2.1 Two-pulse ESEEM -- 2.2 Three-pulse ESEEM -- 2.3 Two-dimensional ESEEM -- 2.4 Practical Aspects of ESEEM Experiments
3 Application-Eseem Studies of Fe(II)/α-Ketoglutarate-Dependent Dioxygenases
Note 200 annual accesses. UkHlHU
Alt author Lukehart, Charles M.
ISBN 9781118625262
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